The Participation of 3,3,3-Trichloro-1-nitroprop-1-ene in the [3 + 2] Cycloaddition Reaction with Selected Nitrile <i>N</i>-Oxides in the Light of the Experimental and MEDT Quantum Chemical Study

The Participation of 3,3,3-Trichloro-1-nitroprop-1-ene in the [3 + 2] Cycloaddition Reaction with Selected Nitrile <i>N</i>-Oxides in the Light of the Experimental and MEDT Quantum Chemical Study

The regioselective <i>zw-type</i> [3 + 2] cycloaddition (32CA) reactions of a series of aryl-substituted nitrile <i>N</i>-oxides (NOs) with trichloronitropropene (TNP) have been both experimentally and theoretically studied within the Molecular Electron Density Theory (MEDT)....

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Autores principales: Karolina Zawadzińska, Mar Ríos-Gutiérrez, Karolina Kula, Przemysław Woliński, Barbara Mirosław, Tomasz Krawczyk, Radomir Jasiński
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
Materias:
[3 + 2] cycloaddition
nitrile oxides
nitroalkenes
reactivity
molecular mechanism
molecular electron density theory
Organic chemistry
QD241-441
Acceso en línea:https://doaj.org/article/a725887f007044daa52102867672fa74
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https://doaj.org/article/a725887f007044daa52102867672fa74

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