Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch

In a symmetric molecule with identical functional groups, selective activation of only one site is challenging. Here, the authors show that 4,4″-diamino-p-terphenyl adsorbs asymmetrically to a metal surface, leading to a change in binding affinity of one of its amine groups.

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Detalles Bibliográficos
Autores principales: Qigang Zhong, Daniel Ebeling, Jalmar Tschakert, Yixuan Gao, Deliang Bao, Shixuan Du, Chen Li, Lifeng Chi, André Schirmeisen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/a8d8571d828042d8b7514222b447959d
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