Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch

Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch

In a symmetric molecule with identical functional groups, selective activation of only one site is challenging. Here, the authors show that 4,4″-diamino-p-terphenyl adsorbs asymmetrically to a metal surface, leading to a change in binding affinity of one of its amine groups.

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Autores principales: Qigang Zhong, Daniel Ebeling, Jalmar Tschakert, Yixuan Gao, Deliang Bao, Shixuan Du, Chen Li, Lifeng Chi, André Schirmeisen
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/a8d8571d828042d8b7514222b447959d
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spelling oai:doaj.org-article:a8d8571d828042d8b7514222b447959d2021-12-02T16:49:17ZSymmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch10.1038/s41467-018-05719-y2041-1723https://doaj.org/article/a8d8571d828042d8b7514222b447959d2018-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05719-yhttps://doaj.org/toc/2041-1723In a symmetric molecule with identical functional groups, selective activation of only one site is challenging. Here, the authors show that 4,4″-diamino-p-terphenyl adsorbs asymmetrically to a metal surface, leading to a change in binding affinity of one of its amine groups.Qigang ZhongDaniel EbelingJalmar TschakertYixuan GaoDeliang BaoShixuan DuChen LiLifeng ChiAndré SchirmeisenNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-7 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Qigang Zhong
Daniel Ebeling
Jalmar Tschakert
Yixuan Gao
Deliang Bao
Shixuan Du
Chen Li
Lifeng Chi
André Schirmeisen
Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch
description In a symmetric molecule with identical functional groups, selective activation of only one site is challenging. Here, the authors show that 4,4″-diamino-p-terphenyl adsorbs asymmetrically to a metal surface, leading to a change in binding affinity of one of its amine groups.
format article
author Qigang Zhong
Daniel Ebeling
Jalmar Tschakert
Yixuan Gao
Deliang Bao
Shixuan Du
Chen Li
Lifeng Chi
André Schirmeisen
author_facet Qigang Zhong
Daniel Ebeling
Jalmar Tschakert
Yixuan Gao
Deliang Bao
Shixuan Du
Chen Li
Lifeng Chi
André Schirmeisen
author_sort Qigang Zhong
title Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch
title_short Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch
title_full Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch
title_fullStr Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch
title_full_unstemmed Symmetry breakdown of 4,4″-diamino-p-terphenyl on a Cu(111) surface by lattice mismatch
title_sort symmetry breakdown of 4,4″-diamino-p-terphenyl on a cu(111) surface by lattice mismatch
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/a8d8571d828042d8b7514222b447959d
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AT danielebeling symmetrybreakdownof44diaminopterphenylonacu111surfacebylatticemismatch
AT jalmartschakert symmetrybreakdownof44diaminopterphenylonacu111surfacebylatticemismatch
AT yixuangao symmetrybreakdownof44diaminopterphenylonacu111surfacebylatticemismatch
AT deliangbao symmetrybreakdownof44diaminopterphenylonacu111surfacebylatticemismatch
AT shixuandu symmetrybreakdownof44diaminopterphenylonacu111surfacebylatticemismatch
AT chenli symmetrybreakdownof44diaminopterphenylonacu111surfacebylatticemismatch
AT lifengchi symmetrybreakdownof44diaminopterphenylonacu111surfacebylatticemismatch
AT andreschirmeisen symmetrybreakdownof44diaminopterphenylonacu111surfacebylatticemismatch
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