Amide nitrogen pyramidalization changes lactam amide spinning
Cis-trans lactam amide rotation is a fundamental process and its understanding might aid molecular design. Here, the authors report the synthesis and study of bicyclic lactams which undergo spin through 360 degrees as in open-chain amides, due to the occurrence of nitrogen pyramidalization.
Enregistré dans:
Auteurs principaux: | , , , , , , , , |
---|---|
Format: | article |
Langue: | EN |
Publié: |
Nature Portfolio
2019
|
Sujets: | |
Accès en ligne: | https://doaj.org/article/abbe06c5c40d47119ae8d500e4816855 |
Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|