Silicon–silicon π single bond

Examples of π single bonds in diradicals are rare, as they are typically unstable. Here, the authors describe a room temperature-stable closed-shell bicyclic tetrasilane that features a Si-Si π single bond between two of the non-adjacent Si centers.

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Autores principales: Soichiro Kyushin, Yoshikuni Kurosaki, Kyohei Otsuka, Haruna Imai, Shintaro Ishida, Toru Kyomen, Minoru Hanaya, Hideyuki Matsumoto
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/ac2c92f277e640fe9f5604a632dc33cb
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