Silicon–silicon π single bond

Silicon–silicon π single bond

Examples of π single bonds in diradicals are rare, as they are typically unstable. Here, the authors describe a room temperature-stable closed-shell bicyclic tetrasilane that features a Si-Si π single bond between two of the non-adjacent Si centers.

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Autores principales: Soichiro Kyushin, Yoshikuni Kurosaki, Kyohei Otsuka, Haruna Imai, Shintaro Ishida, Toru Kyomen, Minoru Hanaya, Hideyuki Matsumoto
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/ac2c92f277e640fe9f5604a632dc33cb
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spelling oai:doaj.org-article:ac2c92f277e640fe9f5604a632dc33cb2021-12-02T16:28:07ZSilicon–silicon π single bond10.1038/s41467-020-17815-z2041-1723https://doaj.org/article/ac2c92f277e640fe9f5604a632dc33cb2020-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17815-zhttps://doaj.org/toc/2041-1723Examples of π single bonds in diradicals are rare, as they are typically unstable. Here, the authors describe a room temperature-stable closed-shell bicyclic tetrasilane that features a Si-Si π single bond between two of the non-adjacent Si centers.Soichiro KyushinYoshikuni KurosakiKyohei OtsukaHaruna ImaiShintaro IshidaToru KyomenMinoru HanayaHideyuki MatsumotoNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Soichiro Kyushin
Yoshikuni Kurosaki
Kyohei Otsuka
Haruna Imai
Shintaro Ishida
Toru Kyomen
Minoru Hanaya
Hideyuki Matsumoto
Silicon–silicon π single bond
description Examples of π single bonds in diradicals are rare, as they are typically unstable. Here, the authors describe a room temperature-stable closed-shell bicyclic tetrasilane that features a Si-Si π single bond between two of the non-adjacent Si centers.
format article
author Soichiro Kyushin
Yoshikuni Kurosaki
Kyohei Otsuka
Haruna Imai
Shintaro Ishida
Toru Kyomen
Minoru Hanaya
Hideyuki Matsumoto
author_facet Soichiro Kyushin
Yoshikuni Kurosaki
Kyohei Otsuka
Haruna Imai
Shintaro Ishida
Toru Kyomen
Minoru Hanaya
Hideyuki Matsumoto
author_sort Soichiro Kyushin
title Silicon–silicon π single bond
title_short Silicon–silicon π single bond
title_full Silicon–silicon π single bond
title_fullStr Silicon–silicon π single bond
title_full_unstemmed Silicon–silicon π single bond
title_sort silicon–silicon π single bond
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/ac2c92f277e640fe9f5604a632dc33cb
work_keys_str_mv AT soichirokyushin siliconsiliconpsinglebond
AT yoshikunikurosaki siliconsiliconpsinglebond
AT kyoheiotsuka siliconsiliconpsinglebond
AT harunaimai siliconsiliconpsinglebond
AT shintaroishida siliconsiliconpsinglebond
AT torukyomen siliconsiliconpsinglebond
AT minoruhanaya siliconsiliconpsinglebond
AT hideyukimatsumoto siliconsiliconpsinglebond
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