Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks

Despite recent success in developing new covalent organic frameworks (COFs) materials, synthesis of chemically stable COFs still remains challenging. Here the authors demonstrate a facile strategy that transforms imine-linked COFs into robust porous aromatic frameworks by kinetically fixing the reve...

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Main Authors:	Xinle Li, Changlin Zhang, Songliang Cai, Xiaohe Lei, Virginia Altoe, Fang Hong, Jeffrey J. Urban, Jim Ciston, Emory M. Chan, Yi Liu
Format:	article
Language:	EN
Published:	Nature Portfolio 2018
Subjects:	Science Q
Online Access:	https://doaj.org/article/b08ff84a9f5e4f7bad0b8bc323ac6a28
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spelling	oai:doaj.org-article:b08ff84a9f5e4f7bad0b8bc323ac6a282021-12-02T17:32:18ZFacile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks10.1038/s41467-018-05462-42041-1723https://doaj.org/article/b08ff84a9f5e4f7bad0b8bc323ac6a282018-07-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-05462-4https://doaj.org/toc/2041-1723Despite recent success in developing new covalent organic frameworks (COFs) materials, synthesis of chemically stable COFs still remains challenging. Here the authors demonstrate a facile strategy that transforms imine-linked COFs into robust porous aromatic frameworks by kinetically fixing the reversible imine linkage via an aza-Diels-Alder cycloaddition reaction.Xinle LiChanglin ZhangSongliang CaiXiaohe LeiVirginia AltoeFang HongJeffrey J. UrbanJim CistonEmory M. ChanYi LiuNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Xinle Li Changlin Zhang Songliang Cai Xiaohe Lei Virginia Altoe Fang Hong Jeffrey J. Urban Jim Ciston Emory M. Chan Yi Liu Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks
description	Despite recent success in developing new covalent organic frameworks (COFs) materials, synthesis of chemically stable COFs still remains challenging. Here the authors demonstrate a facile strategy that transforms imine-linked COFs into robust porous aromatic frameworks by kinetically fixing the reversible imine linkage via an aza-Diels-Alder cycloaddition reaction.
format	article
author	Xinle Li Changlin Zhang Songliang Cai Xiaohe Lei Virginia Altoe Fang Hong Jeffrey J. Urban Jim Ciston Emory M. Chan Yi Liu
author_facet	Xinle Li Changlin Zhang Songliang Cai Xiaohe Lei Virginia Altoe Fang Hong Jeffrey J. Urban Jim Ciston Emory M. Chan Yi Liu
author_sort	Xinle Li
title	Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks
title_short	Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks
title_full	Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks
title_fullStr	Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks
title_full_unstemmed	Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks
title_sort	facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/b08ff84a9f5e4f7bad0b8bc323ac6a28
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Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks

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