Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation
Formation of vicinal, quaternary stereocentres is challenging, but such products are commonly encountered in nature. Here, the authors report a palladium catalysed process to form vicinal quaternary carbons via propargylation, including in enantiopure form when optically active starting materials ar...
Saved in:
Main Authors: | Xin Huang, Shangze Wu, Wangteng Wu, Pengbin Li, Chunling Fu, Shengming Ma |
---|---|
Format: | article |
Language: | EN |
Published: |
Nature Portfolio
2016
|
Subjects: | |
Online Access: | https://doaj.org/article/b6c82ba35c4b4f7f9e58b8e16e735bde |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Similar Items
-
Stereodivergent synthesis of vicinal quaternary-quaternary stereocenters and bioactive hyperolactones
by: Haifeng Zheng, et al.
Published: (2018) -
Palladium-catalysed synthesis of triaryl(heteroaryl)methanes
by: Shuguang Zhang, et al.
Published: (2017) -
Radical asymmetric intramolecular α-cyclopropanation of aldehydes towards bicyclo[3.1.0]hexanes containing vicinal all-carbon quaternary stereocenters
by: Liu Ye, et al.
Published: (2018) -
Enantioselective synthesis of cis-hydrobenzofurans bearing all-carbon quaternary stereocenters and application to total synthesis of (‒)-morphine
by: Qing Zhang, et al.
Published: (2019) -
Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols
by: Deyun Qian, et al.
Published: (2017)