Dichloromethylation of enones by carbon nitride photocatalysis

Long-lived carbon nitride radicals have been used in several photocatalytic reactions. Herein, long-lived potassium poly(heptazine imide) radicals enable synthesis of γ,γ-dichloroketones from enones by addition of CHCl2 moiety, generated from chloroform, to the C=C bond.

Guardado en:
Detalles Bibliográficos
Autores principales: Stefano Mazzanti, Bogdan Kurpil, Bartholomäus Pieber, Markus Antonietti, Aleksandr Savateev
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
Materias:
Q
Acceso en línea:https://doaj.org/article/bba4242e28b04ef993afb5dbcfe5cf0b
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!