Dichloromethylation of enones by carbon nitride photocatalysis

Long-lived carbon nitride radicals have been used in several photocatalytic reactions. Herein, long-lived potassium poly(heptazine imide) radicals enable synthesis of γ,γ-dichloroketones from enones by addition of CHCl2 moiety, generated from chloroform, to the C=C bond.

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Autores principales:	Stefano Mazzanti, Bogdan Kurpil, Bartholomäus Pieber, Markus Antonietti, Aleksandr Savateev
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/bba4242e28b04ef993afb5dbcfe5cf0b
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spelling	oai:doaj.org-article:bba4242e28b04ef993afb5dbcfe5cf0b2021-12-02T15:33:32ZDichloromethylation of enones by carbon nitride photocatalysis10.1038/s41467-020-15131-02041-1723https://doaj.org/article/bba4242e28b04ef993afb5dbcfe5cf0b2020-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15131-0https://doaj.org/toc/2041-1723Long-lived carbon nitride radicals have been used in several photocatalytic reactions. Herein, long-lived potassium poly(heptazine imide) radicals enable synthesis of γ,γ-dichloroketones from enones by addition of CHCl2 moiety, generated from chloroform, to the C=C bond.Stefano MazzantiBogdan KurpilBartholomäus PieberMarkus AntoniettiAleksandr SavateevNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Stefano Mazzanti Bogdan Kurpil Bartholomäus Pieber Markus Antonietti Aleksandr Savateev Dichloromethylation of enones by carbon nitride photocatalysis
description	Long-lived carbon nitride radicals have been used in several photocatalytic reactions. Herein, long-lived potassium poly(heptazine imide) radicals enable synthesis of γ,γ-dichloroketones from enones by addition of CHCl2 moiety, generated from chloroform, to the C=C bond.
format	article
author	Stefano Mazzanti Bogdan Kurpil Bartholomäus Pieber Markus Antonietti Aleksandr Savateev
author_facet	Stefano Mazzanti Bogdan Kurpil Bartholomäus Pieber Markus Antonietti Aleksandr Savateev
author_sort	Stefano Mazzanti
title	Dichloromethylation of enones by carbon nitride photocatalysis
title_short	Dichloromethylation of enones by carbon nitride photocatalysis
title_full	Dichloromethylation of enones by carbon nitride photocatalysis
title_fullStr	Dichloromethylation of enones by carbon nitride photocatalysis
title_full_unstemmed	Dichloromethylation of enones by carbon nitride photocatalysis
title_sort	dichloromethylation of enones by carbon nitride photocatalysis
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/bba4242e28b04ef993afb5dbcfe5cf0b
work_keys_str_mv	AT stefanomazzanti dichloromethylationofenonesbycarbonnitridephotocatalysis AT bogdankurpil dichloromethylationofenonesbycarbonnitridephotocatalysis AT bartholomauspieber dichloromethylationofenonesbycarbonnitridephotocatalysis AT markusantonietti dichloromethylationofenonesbycarbonnitridephotocatalysis AT aleksandrsavateev dichloromethylationofenonesbycarbonnitridephotocatalysis
_version_	1718387104121094144

Dichloromethylation of enones by carbon nitride photocatalysis

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