Dichloromethylation of enones by carbon nitride photocatalysis

Long-lived carbon nitride radicals have been used in several photocatalytic reactions. Herein, long-lived potassium poly(heptazine imide) radicals enable synthesis of γ,γ-dichloroketones from enones by addition of CHCl2 moiety, generated from chloroform, to the C=C bond.

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Auteurs principaux: Stefano Mazzanti, Bogdan Kurpil, Bartholomäus Pieber, Markus Antonietti, Aleksandr Savateev
Format: article
Langue:EN
Publié: Nature Portfolio 2020
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Accès en ligne:https://doaj.org/article/bba4242e28b04ef993afb5dbcfe5cf0b
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