Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides

Arene-fused siloles have attracted interest due to their promising applications in electronic and optoelectronic devices. Here, the authors report Ir(III)-catalyzed cycloaromatization of ortho-alkynylaryl vinylsilanes with arylsulfonyl azides via α-silyl radical Smiles rearrangement for accessing na...

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Autores principales: Fengjuan Chen, Youxiang Shao, Mengke Li, Can Yang, Shi-Jian Su, Huanfeng Jiang, Zhuofeng Ke, Wei Zeng
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/bc54b08e84ca4efa9c810aa163b1d582
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