Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides

Arene-fused siloles have attracted interest due to their promising applications in electronic and optoelectronic devices. Here, the authors report Ir(III)-catalyzed cycloaromatization of ortho-alkynylaryl vinylsilanes with arylsulfonyl azides via α-silyl radical Smiles rearrangement for accessing na...

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Main Authors:	Fengjuan Chen, Youxiang Shao, Mengke Li, Can Yang, Shi-Jian Su, Huanfeng Jiang, Zhuofeng Ke, Wei Zeng
Format:	article
Language:	EN
Published:	Nature Portfolio 2021
Subjects:	Science Q
Online Access:	https://doaj.org/article/bc54b08e84ca4efa9c810aa163b1d582
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spelling	oai:doaj.org-article:bc54b08e84ca4efa9c810aa163b1d5822021-12-02T15:56:47ZPhotocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides10.1038/s41467-021-23326-22041-1723https://doaj.org/article/bc54b08e84ca4efa9c810aa163b1d5822021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23326-2https://doaj.org/toc/2041-1723Arene-fused siloles have attracted interest due to their promising applications in electronic and optoelectronic devices. Here, the authors report Ir(III)-catalyzed cycloaromatization of ortho-alkynylaryl vinylsilanes with arylsulfonyl azides via α-silyl radical Smiles rearrangement for accessing naphthyl-fused benzosiloles under visible-light photoredox conditions.Fengjuan ChenYouxiang ShaoMengke LiCan YangShi-Jian SuHuanfeng JiangZhuofeng KeWei ZengNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Fengjuan Chen Youxiang Shao Mengke Li Can Yang Shi-Jian Su Huanfeng Jiang Zhuofeng Ke Wei Zeng Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides
description	Arene-fused siloles have attracted interest due to their promising applications in electronic and optoelectronic devices. Here, the authors report Ir(III)-catalyzed cycloaromatization of ortho-alkynylaryl vinylsilanes with arylsulfonyl azides via α-silyl radical Smiles rearrangement for accessing naphthyl-fused benzosiloles under visible-light photoredox conditions.
format	article
author	Fengjuan Chen Youxiang Shao Mengke Li Can Yang Shi-Jian Su Huanfeng Jiang Zhuofeng Ke Wei Zeng
author_facet	Fengjuan Chen Youxiang Shao Mengke Li Can Yang Shi-Jian Su Huanfeng Jiang Zhuofeng Ke Wei Zeng
author_sort	Fengjuan Chen
title	Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides
title_short	Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides
title_full	Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides
title_fullStr	Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides
title_full_unstemmed	Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides
title_sort	photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/bc54b08e84ca4efa9c810aa163b1d582
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Photocatalyzed cycloaromatization of vinylsilanes with arylsulfonylazides

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