Oxidation of difluorocarbene and subsequent trifluoromethoxylation
Difluorocarbene is a versatile and efficient intermediate for fluorine incorporation. Here, the authors show that difluorocarbene can be oxidized to carbonyl fluoride and this process is confirmed in 18O-trifluoromethoxylation reactions, by observation of AgOCF3 species and theory.
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Main Authors: | Jiao Yu, Jin-Hong Lin, Donghai Yu, Ruobing Du, Ji-Chang Xiao |
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Format: | article |
Language: | EN |
Published: |
Nature Portfolio
2019
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Subjects: | |
Online Access: | https://doaj.org/article/c07c235c8ba24b71b97241c47c4dd27f |
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