Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives

Baird’s rule applies to cyclic π-conjugated molecules in their excited state, yet a quantification of the involved energetics is elusive. Here, the authors show the ring inversion kinetics of two nonplanar and chiral [4n]annulenes to support Baird’s rule from an energetic point of view.

Guardado en:
Detalles Bibliográficos
Autores principales: Michihisa Ueda, Kjell Jorner, Young Mo Sung, Tadashi Mori, Qi Xiao, Dongho Kim, Henrik Ottosson, Takuzo Aida, Yoshimitsu Itoh
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
Materias:
Q
Acceso en línea:https://doaj.org/article/c6add6e0a20c4c13ab7a1fd6ca022d7b
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!