Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives
Baird’s rule applies to cyclic π-conjugated molecules in their excited state, yet a quantification of the involved energetics is elusive. Here, the authors show the ring inversion kinetics of two nonplanar and chiral [4n]annulenes to support Baird’s rule from an energetic point of view.
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| Main Authors: | , , , , , , , , |
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| Format: | article |
| Language: | EN |
| Published: |
Nature Portfolio
2017
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| Subjects: | |
| Online Access: | https://doaj.org/article/c6add6e0a20c4c13ab7a1fd6ca022d7b |
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