Suppressing hydrogen peroxide generation to achieve oxygen-insensitivity of a [NiFe] hydrogenase in redox active films

Oxidative degradation impedes practical applications of highly active but fragile catalysts. Here the authors show that combining a protection matrix for O2 reduction and hydrogen peroxide decomposition stabilizes highly O2-sensitive hydrogenase in the harsh oxidative conditions of operating fuel ce...

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Auteurs principaux: Huaiguang Li, Ute Münchberg, Alaa A. Oughli, Darren Buesen, Wolfgang Lubitz, Erik Freier, Nicolas Plumeré
Format: article
Langue:EN
Publié: Nature Portfolio 2020
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Accès en ligne:https://doaj.org/article/c8dfcdbecf404d3ca4aae12c40bcbe41
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