Synthesis and assembly of extended quintulene

Quintulene, a quintuple non-graphitic cycloarene, is challenging to synthesize. Here, the authors synthesize and characterize the cone-shaped extended quintulene and its bilayer dimer, and disclose its dimerization as an entropy-driven, second-order reaction with a substantial activation energy.

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Auteurs principaux: Hao Hou, Xin-Jing Zhao, Chun Tang, Yang-Yang Ju, Ze-Ying Deng, Xin-Rong Wang, Liu-Bin Feng, Dong-Hai Lin, Xu Hou, Akimitsu Narita, Klaus Müllen, Yuan-Zhi Tan
Format: article
Langue:EN
Publié: Nature Portfolio 2020
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Accès en ligne:https://doaj.org/article/cf7210346c71471fb5466ca6d60a15b1
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