Synthesis and assembly of extended quintulene

Quintulene, a quintuple non-graphitic cycloarene, is challenging to synthesize. Here, the authors synthesize and characterize the cone-shaped extended quintulene and its bilayer dimer, and disclose its dimerization as an entropy-driven, second-order reaction with a substantial activation energy.

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Autores principales:	Hao Hou, Xin-Jing Zhao, Chun Tang, Yang-Yang Ju, Ze-Ying Deng, Xin-Rong Wang, Liu-Bin Feng, Dong-Hai Lin, Xu Hou, Akimitsu Narita, Klaus Müllen, Yuan-Zhi Tan
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/cf7210346c71471fb5466ca6d60a15b1
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spelling	oai:doaj.org-article:cf7210346c71471fb5466ca6d60a15b12021-12-02T17:06:12ZSynthesis and assembly of extended quintulene10.1038/s41467-020-17691-72041-1723https://doaj.org/article/cf7210346c71471fb5466ca6d60a15b12020-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-17691-7https://doaj.org/toc/2041-1723Quintulene, a quintuple non-graphitic cycloarene, is challenging to synthesize. Here, the authors synthesize and characterize the cone-shaped extended quintulene and its bilayer dimer, and disclose its dimerization as an entropy-driven, second-order reaction with a substantial activation energy.Hao HouXin-Jing ZhaoChun TangYang-Yang JuZe-Ying DengXin-Rong WangLiu-Bin FengDong-Hai LinXu HouAkimitsu NaritaKlaus MüllenYuan-Zhi TanNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Hao Hou Xin-Jing Zhao Chun Tang Yang-Yang Ju Ze-Ying Deng Xin-Rong Wang Liu-Bin Feng Dong-Hai Lin Xu Hou Akimitsu Narita Klaus Müllen Yuan-Zhi Tan Synthesis and assembly of extended quintulene
description	Quintulene, a quintuple non-graphitic cycloarene, is challenging to synthesize. Here, the authors synthesize and characterize the cone-shaped extended quintulene and its bilayer dimer, and disclose its dimerization as an entropy-driven, second-order reaction with a substantial activation energy.
format	article
author	Hao Hou Xin-Jing Zhao Chun Tang Yang-Yang Ju Ze-Ying Deng Xin-Rong Wang Liu-Bin Feng Dong-Hai Lin Xu Hou Akimitsu Narita Klaus Müllen Yuan-Zhi Tan
author_facet	Hao Hou Xin-Jing Zhao Chun Tang Yang-Yang Ju Ze-Ying Deng Xin-Rong Wang Liu-Bin Feng Dong-Hai Lin Xu Hou Akimitsu Narita Klaus Müllen Yuan-Zhi Tan
author_sort	Hao Hou
title	Synthesis and assembly of extended quintulene
title_short	Synthesis and assembly of extended quintulene
title_full	Synthesis and assembly of extended quintulene
title_fullStr	Synthesis and assembly of extended quintulene
title_full_unstemmed	Synthesis and assembly of extended quintulene
title_sort	synthesis and assembly of extended quintulene
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/cf7210346c71471fb5466ca6d60a15b1
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Synthesis and assembly of extended quintulene

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