Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules

Homochiral molecular capsules offer potential applications in chiral separation and stereospecific catalysis. Here, by pre-resolution of Δ/Λ-metalloligand precursors, the authors are able to assemble enantiopure supramolecular cages capable of stereoselective host-guest behaviour.

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Detalles Bibliográficos
Autores principales: Kai Wu, Kang Li, Ya-Jun Hou, Mei Pan, Lu-Yin Zhang, Ling Chen, Cheng-Yong Su
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Q
Acceso en línea:https://doaj.org/article/d18a1d787ba84fe7b245075bbb678013
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