Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules

Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules

Homochiral molecular capsules offer potential applications in chiral separation and stereospecific catalysis. Here, by pre-resolution of Δ/Λ-metalloligand precursors, the authors are able to assemble enantiopure supramolecular cages capable of stereoselective host-guest behaviour.

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Autores principales: Kai Wu, Kang Li, Ya-Jun Hou, Mei Pan, Lu-Yin Zhang, Ling Chen, Cheng-Yong Su
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/d18a1d787ba84fe7b245075bbb678013
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spelling oai:doaj.org-article:d18a1d787ba84fe7b245075bbb6780132021-12-02T17:31:35ZHomochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules10.1038/ncomms104872041-1723https://doaj.org/article/d18a1d787ba84fe7b245075bbb6780132016-02-01T00:00:00Zhttps://doi.org/10.1038/ncomms10487https://doaj.org/toc/2041-1723Homochiral molecular capsules offer potential applications in chiral separation and stereospecific catalysis. Here, by pre-resolution of Δ/Λ-metalloligand precursors, the authors are able to assemble enantiopure supramolecular cages capable of stereoselective host-guest behaviour.Kai WuKang LiYa-Jun HouMei PanLu-Yin ZhangLing ChenCheng-Yong SuNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-10 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Kai Wu
Kang Li
Ya-Jun Hou
Mei Pan
Lu-Yin Zhang
Ling Chen
Cheng-Yong Su
Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules
description Homochiral molecular capsules offer potential applications in chiral separation and stereospecific catalysis. Here, by pre-resolution of Δ/Λ-metalloligand precursors, the authors are able to assemble enantiopure supramolecular cages capable of stereoselective host-guest behaviour.
format article
author Kai Wu
Kang Li
Ya-Jun Hou
Mei Pan
Lu-Yin Zhang
Ling Chen
Cheng-Yong Su
author_facet Kai Wu
Kang Li
Ya-Jun Hou
Mei Pan
Lu-Yin Zhang
Ling Chen
Cheng-Yong Su
author_sort Kai Wu
title Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules
title_short Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules
title_full Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules
title_fullStr Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules
title_full_unstemmed Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules
title_sort homochiral d4-symmetric metal–organic cages from stereogenic ru(ii) metalloligands for effective enantioseparation of atropisomeric molecules
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/d18a1d787ba84fe7b245075bbb678013
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AT kangli homochirald4symmetricmetalorganiccagesfromstereogenicruiimetalloligandsforeffectiveenantioseparationofatropisomericmolecules
AT yajunhou homochirald4symmetricmetalorganiccagesfromstereogenicruiimetalloligandsforeffectiveenantioseparationofatropisomericmolecules
AT meipan homochirald4symmetricmetalorganiccagesfromstereogenicruiimetalloligandsforeffectiveenantioseparationofatropisomericmolecules
AT luyinzhang homochirald4symmetricmetalorganiccagesfromstereogenicruiimetalloligandsforeffectiveenantioseparationofatropisomericmolecules
AT lingchen homochirald4symmetricmetalorganiccagesfromstereogenicruiimetalloligandsforeffectiveenantioseparationofatropisomericmolecules
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