Homochiral D4-symmetric metal–organic cages from stereogenic Ru(II) metalloligands for effective enantioseparation of atropisomeric molecules
Homochiral molecular capsules offer potential applications in chiral separation and stereospecific catalysis. Here, by pre-resolution of Δ/Λ-metalloligand precursors, the authors are able to assemble enantiopure supramolecular cages capable of stereoselective host-guest behaviour.
Guardado en:
Autores principales: | Kai Wu, Kang Li, Ya-Jun Hou, Mei Pan, Lu-Yin Zhang, Ling Chen, Cheng-Yong Su |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2016
|
Materias: | |
Acceso en línea: | https://doaj.org/article/d18a1d787ba84fe7b245075bbb678013 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Metal-free oxidative cross-coupling enabled practical synthesis of atropisomeric QUINOL and its derivatives
por: Peng-Ying Jiang, et al.
Publicado: (2021) -
Single-molecule insights into surface-mediated homochirality in hierarchical peptide assembly
por: Yumin Chen, et al.
Publicado: (2018) -
Anomalously rotary polarization discovered in homochiral organic ferroelectrics
por: Peng-Fei Li, et al.
Publicado: (2016) -
Chiroptical activity of hydroxycarboxylic acids with implications for the origin of biological homochirality
por: Jana Bocková, et al.
Publicado: (2021) -
Development of a Chiral Capillary Electrophoresis Method for the Enantioseparation of Verapamil Using Cyclodextrins as Chiral Selectors and Experimental Design Optimization
por: Melania Cârcu-Dobrin, et al.
Publicado: (2021)