Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain
The surface oxygen storage capacity is an important metric of catalytic activity, but its dependence on strain is not well characterized. Here, the authors show the surface oxygen nonstoichiometry in coherently strained CeO2-δ films increases non-monotonically with biaxial strain.
Saved in:
Main Authors: | , , , , , , , , , , |
---|---|
Format: | article |
Language: | EN |
Published: |
Nature Portfolio
2017
|
Subjects: | |
Online Access: | https://doaj.org/article/d263b7387b6149c1a05806e5b6313eb9 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
oai:doaj.org-article:d263b7387b6149c1a05806e5b6313eb9 |
---|---|
record_format |
dspace |
spelling |
oai:doaj.org-article:d263b7387b6149c1a05806e5b6313eb92021-12-02T14:40:56ZEquilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain10.1038/ncomms153602041-1723https://doaj.org/article/d263b7387b6149c1a05806e5b6313eb92017-05-01T00:00:00Zhttps://doi.org/10.1038/ncomms15360https://doaj.org/toc/2041-1723The surface oxygen storage capacity is an important metric of catalytic activity, but its dependence on strain is not well characterized. Here, the authors show the surface oxygen nonstoichiometry in coherently strained CeO2-δ films increases non-monotonically with biaxial strain.Chirranjeevi Balaji GopalMax García-MelchorSang Chul LeeYezhou ShiAndrey ShavorskiyMatteo MontiZixuan GuanRobert SinclairHendrik BluhmAleksandra VojvodicWilliam C. ChuehNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-12 (2017) |
institution |
DOAJ |
collection |
DOAJ |
language |
EN |
topic |
Science Q |
spellingShingle |
Science Q Chirranjeevi Balaji Gopal Max García-Melchor Sang Chul Lee Yezhou Shi Andrey Shavorskiy Matteo Monti Zixuan Guan Robert Sinclair Hendrik Bluhm Aleksandra Vojvodic William C. Chueh Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain |
description |
The surface oxygen storage capacity is an important metric of catalytic activity, but its dependence on strain is not well characterized. Here, the authors show the surface oxygen nonstoichiometry in coherently strained CeO2-δ films increases non-monotonically with biaxial strain. |
format |
article |
author |
Chirranjeevi Balaji Gopal Max García-Melchor Sang Chul Lee Yezhou Shi Andrey Shavorskiy Matteo Monti Zixuan Guan Robert Sinclair Hendrik Bluhm Aleksandra Vojvodic William C. Chueh |
author_facet |
Chirranjeevi Balaji Gopal Max García-Melchor Sang Chul Lee Yezhou Shi Andrey Shavorskiy Matteo Monti Zixuan Guan Robert Sinclair Hendrik Bluhm Aleksandra Vojvodic William C. Chueh |
author_sort |
Chirranjeevi Balaji Gopal |
title |
Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain |
title_short |
Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain |
title_full |
Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain |
title_fullStr |
Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain |
title_full_unstemmed |
Equilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain |
title_sort |
equilibrium oxygen storage capacity of ultrathin ceo2-δ depends non-monotonically on large biaxial strain |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/d263b7387b6149c1a05806e5b6313eb9 |
work_keys_str_mv |
AT chirranjeevibalajigopal equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT maxgarciamelchor equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT sangchullee equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT yezhoushi equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT andreyshavorskiy equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT matteomonti equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT zixuanguan equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT robertsinclair equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT hendrikbluhm equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT aleksandravojvodic equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain AT williamcchueh equilibriumoxygenstoragecapacityofultrathinceo2ddependsnonmonotonicallyonlargebiaxialstrain |
_version_ |
1718390082835054592 |