Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles

Identifying distinct cyclometallation pathways is essential to new types of C-H activation and functionalization in organic synthesis. Here, the authors show the activation of an olefinic C-H bond geminal to the directing group via four- to eight-membered exo-palladacycles with broad substrate scope...

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Auteurs principaux: Keke Meng, Tingyan Li, Chunbing Yu, Cong Shen, Jian Zhang, Guofu Zhong
Format: article
Langue:EN
Publié: Nature Portfolio 2019
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Accès en ligne:https://doaj.org/article/d5555ceb29e048fca9939331689171a4
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