Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles

Identifying distinct cyclometallation pathways is essential to new types of C-H activation and functionalization in organic synthesis. Here, the authors show the activation of an olefinic C-H bond geminal to the directing group via four- to eight-membered exo-palladacycles with broad substrate scope...

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Autores principales:	Keke Meng, Tingyan Li, Chunbing Yu, Cong Shen, Jian Zhang, Guofu Zhong
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/d5555ceb29e048fca9939331689171a4
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spelling	oai:doaj.org-article:d5555ceb29e048fca9939331689171a42021-12-02T17:31:36ZGeminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles10.1038/s41467-019-13098-12041-1723https://doaj.org/article/d5555ceb29e048fca9939331689171a42019-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-13098-1https://doaj.org/toc/2041-1723Identifying distinct cyclometallation pathways is essential to new types of C-H activation and functionalization in organic synthesis. Here, the authors show the activation of an olefinic C-H bond geminal to the directing group via four- to eight-membered exo-palladacycles with broad substrate scope.Keke MengTingyan LiChunbing YuCong ShenJian ZhangGuofu ZhongNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-10 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Keke Meng Tingyan Li Chunbing Yu Cong Shen Jian Zhang Guofu Zhong Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles
description	Identifying distinct cyclometallation pathways is essential to new types of C-H activation and functionalization in organic synthesis. Here, the authors show the activation of an olefinic C-H bond geminal to the directing group via four- to eight-membered exo-palladacycles with broad substrate scope.
format	article
author	Keke Meng Tingyan Li Chunbing Yu Cong Shen Jian Zhang Guofu Zhong
author_facet	Keke Meng Tingyan Li Chunbing Yu Cong Shen Jian Zhang Guofu Zhong
author_sort	Keke Meng
title	Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles
title_short	Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles
title_full	Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles
title_fullStr	Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles
title_full_unstemmed	Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles
title_sort	geminal group-directed olefinic c-h functionalization via four- to eight-membered exo-metallocycles
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/d5555ceb29e048fca9939331689171a4
work_keys_str_mv	AT kekemeng geminalgroupdirectedolefinicchfunctionalizationviafourtoeightmemberedexometallocycles AT tingyanli geminalgroupdirectedolefinicchfunctionalizationviafourtoeightmemberedexometallocycles AT chunbingyu geminalgroupdirectedolefinicchfunctionalizationviafourtoeightmemberedexometallocycles AT congshen geminalgroupdirectedolefinicchfunctionalizationviafourtoeightmemberedexometallocycles AT jianzhang geminalgroupdirectedolefinicchfunctionalizationviafourtoeightmemberedexometallocycles AT guofuzhong geminalgroupdirectedolefinicchfunctionalizationviafourtoeightmemberedexometallocycles
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Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles

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