Geminal group-directed olefinic C-H functionalization via four- to eight-membered exo-metallocycles
Identifying distinct cyclometallation pathways is essential to new types of C-H activation and functionalization in organic synthesis. Here, the authors show the activation of an olefinic C-H bond geminal to the directing group via four- to eight-membered exo-palladacycles with broad substrate scope...
Guardado en:
Autores principales: | Keke Meng, Tingyan Li, Chunbing Yu, Cong Shen, Jian Zhang, Guofu Zhong |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2019
|
Materias: | |
Acceso en línea: | https://doaj.org/article/d5555ceb29e048fca9939331689171a4 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Graphene-like nanoribbons periodically embedded with four- and eight-membered rings
por: Meizhuang Liu, et al.
Publicado: (2017) -
A three-membered ring approach to carbonyl olefination
por: Supaporn Niyomchon, et al.
Publicado: (2017) -
Single-molecule level control of host-guest interactions in metallocycle-C60 complexes
por: Jian-Hong Tang, et al.
Publicado: (2019) -
Directed transforming of coke to active intermediates in methanol-to-olefins catalyst to boost light olefins selectivity
por: Jibin Zhou, et al.
Publicado: (2021) -
The combination of asymmetric hydrogenation of olefins and direct reductive amination
por: Shuai Yuan, et al.
Publicado: (2020)