Synergistic catalysis for cascade allylation and 2-aza-cope rearrangement of azomethine ylides
Metallated azomethine ylides are commonly used for the construction of N-heterocycles and α-amino acids. Here, the authors report a synergistic Cu/Ir-catalytic system that converts aldimine esters to a variety of chiral homoallylic amines via a cascade allylation/2-aza-Cope rearrangement.
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| Autores principales: | , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2019
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/d66f8b0ef64849baa3af7b38ea218790 |
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