Hydroxylamine-mediated C–C amination via an aza-hock rearrangement

Syntheses of anilines occur through a variety of methods, most requiring transition metals or multiple steps. Here the authors disclose a protocol to form anilines from benzyl alcohols via an aza-Hock rearrangement that uses only a sulfonyl hydroxylamine and solvent.

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Bibliographic Details
Main Authors: Tao Wang, Philipp M. Stein, Hongwei Shi, Chao Hu, Matthias Rudolph, A. Stephen K. Hashmi
Format: article
Language:EN
Published: Nature Portfolio 2021
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Online Access:https://doaj.org/article/e0383b8fccc844379430948803529032
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