Hydroxylamine-mediated C–C amination via an aza-hock rearrangement

Syntheses of anilines occur through a variety of methods, most requiring transition metals or multiple steps. Here the authors disclose a protocol to form anilines from benzyl alcohols via an aza-Hock rearrangement that uses only a sulfonyl hydroxylamine and solvent.

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Autores principales:	Tao Wang, Philipp M. Stein, Hongwei Shi, Chao Hu, Matthias Rudolph, A. Stephen K. Hashmi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e0383b8fccc844379430948803529032
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spelling	oai:doaj.org-article:e0383b8fccc8443794309488035290322021-12-05T12:21:38ZHydroxylamine-mediated C–C amination via an aza-hock rearrangement10.1038/s41467-021-27271-y2041-1723https://doaj.org/article/e0383b8fccc8443794309488035290322021-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-27271-yhttps://doaj.org/toc/2041-1723Syntheses of anilines occur through a variety of methods, most requiring transition metals or multiple steps. Here the authors disclose a protocol to form anilines from benzyl alcohols via an aza-Hock rearrangement that uses only a sulfonyl hydroxylamine and solvent.Tao WangPhilipp M. SteinHongwei ShiChao HuMatthias RudolphA. Stephen K. HashmiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Tao Wang Philipp M. Stein Hongwei Shi Chao Hu Matthias Rudolph A. Stephen K. Hashmi Hydroxylamine-mediated C–C amination via an aza-hock rearrangement
description	Syntheses of anilines occur through a variety of methods, most requiring transition metals or multiple steps. Here the authors disclose a protocol to form anilines from benzyl alcohols via an aza-Hock rearrangement that uses only a sulfonyl hydroxylamine and solvent.
format	article
author	Tao Wang Philipp M. Stein Hongwei Shi Chao Hu Matthias Rudolph A. Stephen K. Hashmi
author_facet	Tao Wang Philipp M. Stein Hongwei Shi Chao Hu Matthias Rudolph A. Stephen K. Hashmi
author_sort	Tao Wang
title	Hydroxylamine-mediated C–C amination via an aza-hock rearrangement
title_short	Hydroxylamine-mediated C–C amination via an aza-hock rearrangement
title_full	Hydroxylamine-mediated C–C amination via an aza-hock rearrangement
title_fullStr	Hydroxylamine-mediated C–C amination via an aza-hock rearrangement
title_full_unstemmed	Hydroxylamine-mediated C–C amination via an aza-hock rearrangement
title_sort	hydroxylamine-mediated c–c amination via an aza-hock rearrangement
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/e0383b8fccc844379430948803529032
work_keys_str_mv	AT taowang hydroxylaminemediatedccaminationviaanazahockrearrangement AT philippmstein hydroxylaminemediatedccaminationviaanazahockrearrangement AT hongweishi hydroxylaminemediatedccaminationviaanazahockrearrangement AT chaohu hydroxylaminemediatedccaminationviaanazahockrearrangement AT matthiasrudolph hydroxylaminemediatedccaminationviaanazahockrearrangement AT astephenkhashmi hydroxylaminemediatedccaminationviaanazahockrearrangement
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Hydroxylamine-mediated C–C amination via an aza-hock rearrangement

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