Hydroxylamine-mediated C–C amination via an aza-hock rearrangement
Syntheses of anilines occur through a variety of methods, most requiring transition metals or multiple steps. Here the authors disclose a protocol to form anilines from benzyl alcohols via an aza-Hock rearrangement that uses only a sulfonyl hydroxylamine and solvent.
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Autores principales: | Tao Wang, Philipp M. Stein, Hongwei Shi, Chao Hu, Matthias Rudolph, A. Stephen K. Hashmi |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2021
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Materias: | |
Acceso en línea: | https://doaj.org/article/e0383b8fccc844379430948803529032 |
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