Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters

Metallaphototoredox catalysis has been rarely applied to reductive cross-couplings, in contrast to typical redox-neutral methods. Here, the authors report a mild Ni/photoredox-catalyzed reductive cross-coupling of aryl iodides and α-chloroboranes, further enriching the metallaphotoredox chemistry.

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Autores principales: Purui Zheng, Pan Zhou, Dong Wang, Wenhao Xu, Hepan Wang, Tao XU
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/e16c5b817d2d4cce9ea7a8f0af99cf7f
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