Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters

Metallaphototoredox catalysis has been rarely applied to reductive cross-couplings, in contrast to typical redox-neutral methods. Here, the authors report a mild Ni/photoredox-catalyzed reductive cross-coupling of aryl iodides and α-chloroboranes, further enriching the metallaphotoredox chemistry.

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Autores principales:	Purui Zheng, Pan Zhou, Dong Wang, Wenhao Xu, Hepan Wang, Tao XU
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e16c5b817d2d4cce9ea7a8f0af99cf7f
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spelling	oai:doaj.org-article:e16c5b817d2d4cce9ea7a8f0af99cf7f2021-12-02T15:52:28ZDual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters10.1038/s41467-021-21947-12041-1723https://doaj.org/article/e16c5b817d2d4cce9ea7a8f0af99cf7f2021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-21947-1https://doaj.org/toc/2041-1723Metallaphototoredox catalysis has been rarely applied to reductive cross-couplings, in contrast to typical redox-neutral methods. Here, the authors report a mild Ni/photoredox-catalyzed reductive cross-coupling of aryl iodides and α-chloroboranes, further enriching the metallaphotoredox chemistry.Purui ZhengPan ZhouDong WangWenhao XuHepan WangTao XUNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Purui Zheng Pan Zhou Dong Wang Wenhao Xu Hepan Wang Tao XU Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters
description	Metallaphototoredox catalysis has been rarely applied to reductive cross-couplings, in contrast to typical redox-neutral methods. Here, the authors report a mild Ni/photoredox-catalyzed reductive cross-coupling of aryl iodides and α-chloroboranes, further enriching the metallaphotoredox chemistry.
format	article
author	Purui Zheng Pan Zhou Dong Wang Wenhao Xu Hepan Wang Tao XU
author_facet	Purui Zheng Pan Zhou Dong Wang Wenhao Xu Hepan Wang Tao XU
author_sort	Purui Zheng
title	Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters
title_short	Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters
title_full	Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters
title_fullStr	Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters
title_full_unstemmed	Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters
title_sort	dual ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/e16c5b817d2d4cce9ea7a8f0af99cf7f
work_keys_str_mv	AT puruizheng dualniphotoredoxcatalyzedasymmetriccrosscouplingtoaccesschiralbenzylicboronicesters AT panzhou dualniphotoredoxcatalyzedasymmetriccrosscouplingtoaccesschiralbenzylicboronicesters AT dongwang dualniphotoredoxcatalyzedasymmetriccrosscouplingtoaccesschiralbenzylicboronicesters AT wenhaoxu dualniphotoredoxcatalyzedasymmetriccrosscouplingtoaccesschiralbenzylicboronicesters AT hepanwang dualniphotoredoxcatalyzedasymmetriccrosscouplingtoaccesschiralbenzylicboronicesters AT taoxu dualniphotoredoxcatalyzedasymmetriccrosscouplingtoaccesschiralbenzylicboronicesters
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Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters

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