Exciton-driven change of phonon modes causes strong temperature dependent bandgap shift in nanoclusters

The bandgap of nanostructures usually follows the bulk value upon temperature change. Here, the authors find that in small nanocrystals a weakening of the bonds due to optical excitation causes a pronounced phonon shift, leading to a drastic enhancement of the bandgap’s temperature dependence.

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Auteurs principaux: Franziska Muckel, Severin Lorenz, Jiwoong Yang, Taufik Adi Nugraha, Emilio Scalise, Taeghwan Hyeon, Stefan Wippermann, Gerd Bacher
Format: article
Langue:EN
Publié: Nature Portfolio 2020
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Accès en ligne:https://doaj.org/article/e33292bd4c844f4a9e17e51bcdfbcdc0
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