Exciton-driven change of phonon modes causes strong temperature dependent bandgap shift in nanoclusters

The bandgap of nanostructures usually follows the bulk value upon temperature change. Here, the authors find that in small nanocrystals a weakening of the bonds due to optical excitation causes a pronounced phonon shift, leading to a drastic enhancement of the bandgap’s temperature dependence.

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Detalles Bibliográficos
Autores principales: Franziska Muckel, Severin Lorenz, Jiwoong Yang, Taufik Adi Nugraha, Emilio Scalise, Taeghwan Hyeon, Stefan Wippermann, Gerd Bacher
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/e33292bd4c844f4a9e17e51bcdfbcdc0
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Sumario:The bandgap of nanostructures usually follows the bulk value upon temperature change. Here, the authors find that in small nanocrystals a weakening of the bonds due to optical excitation causes a pronounced phonon shift, leading to a drastic enhancement of the bandgap’s temperature dependence.