Synthesis and Catalytic Properties of Novel Ruthenacarboranes Based on <i>nido</i>-[5-Me-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>]<sup>2−</sup> and <i>nido</i>-[5,6-Me<sub>2</sub>-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>9</sub>]<sup>2−</sup> Dicarbollide Ligands

Synthesis and Catalytic Properties of Novel Ruthenacarboranes Based on <i>nido</i>-[5-Me-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>]<sup>2−</sup> and <i>nido</i>-[5,6-Me<sub>2</sub>-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>9</sub>]<sup>2−</sup> Dicarbollide Ligands

The effect of methyl substituents in the lower belt of dicarbollide ligands on the redox potential of ruthenacarboranes based thereof, as well as the ability of the metallacarboranes obtained to catalyze radical polymerization with atom transfer were studied. For this purpose, a new approach to the...

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Bibliographic Details
Main Authors: Ivan D. Grishin, Anastasiya M. Zimina, Sergey A. Anufriev, Nadezhda A. Knyazeva, Alexander V. Piskunov, Fedor M. Dolgushin, Igor B. Sivaev
Format: article
Language:EN
Published: MDPI AG 2021
Subjects:
ruthenacarborane
synthesis
X-ray structure
electrochemistry
ATRP catalysis
Chemical technology
TP1-1185
Chemistry
QD1-999
Online Access:https://doaj.org/article/e5f07f312214410187db28da34f8edbe
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