Synthesis and Catalytic Properties of Novel Ruthenacarboranes Based on <i>nido</i>-[5-Me-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>10</sub>]<sup>2−</sup> and <i>nido</i>-[5,6-Me<sub>2</sub>-7,8-C<sub>2</sub>B<sub>9</sub>H<sub>9</sub>]<sup>2−</sup> Dicarbollide Ligands
The effect of methyl substituents in the lower belt of dicarbollide ligands on the redox potential of ruthenacarboranes based thereof, as well as the ability of the metallacarboranes obtained to catalyze radical polymerization with atom transfer were studied. For this purpose, a new approach to the...
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| Main Authors: | , , , , , , |
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| Format: | article |
| Language: | EN |
| Published: |
MDPI AG
2021
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| Subjects: | |
| Online Access: | https://doaj.org/article/e5f07f312214410187db28da34f8edbe |
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