CH2 Linkage Effects on the Reactivity of Bis(aminophosphine)–Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols

Abstract A novel ruthenium complex binding to two subtly different aminophosphine ligands, (o-PPh2C6H4CH2NH2)(o-PPh2C6H4NH2)RuCl2, was successfully isolated. This bis(aminophosphine)–ruthenium complex shows efficient activity in both dimethyl oxalate (DMO) and methyl benzoate (MB) hydrogenation. On...

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Autores principales: Xiaolong Fang, Mingjun Sun, Jianwei Zheng, Bin Li, Linmin Ye, Xiaoping Wang, Zexing Cao, Hongping Zhu, Youzhu Yuan
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/eb96cef5dc944821b337e7fb530eba84
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