Basicity as a Thermodynamic Descriptor of Carbanions Reactivity with Carbon Dioxide: Application to the Carboxylation of α,β-Unsaturated Ketones

Basicity as a Thermodynamic Descriptor of Carbanions Reactivity with Carbon Dioxide: Application to the Carboxylation of α,β-Unsaturated Ketones

The utilization of carbon dioxide as a raw material represents nowadays an appealing strategy in the renewable energy, organic synthesis, and green chemistry fields. Besides reduction strategies, carbon dioxide can be exploited as a single-carbon-atom building block through its fixation into organic...

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Bibliographic Details
Main Authors: Pietro Franceschi, Catia Nicoletti, Ruggero Bonetto, Marcella Bonchio, Mirco Natali, Luca Dell’Amico, Andrea Sartorel
Format: article
Language:EN
Published: Frontiers Media S.A. 2021
Subjects:
carbon dioxide fixation
thermodynamic analysis
DFT calculations
reaction intermediates
unsaturated carbonyl
Chemistry
QD1-999
Online Access:https://doaj.org/article/f0872061b4894bdcb749022e0694910b
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