Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates
Rare-earth perovskite nickelates show intriguing metal–insulator transitions, whose mechanism remains elusive. Here, Bisogni et al. evidenced a 3d8 Ni configuration together with abundance of oxygen 2p holes in the ground state of a NdNiO3thin film, suggesting a negative charge-transfer scenario.
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| Auteurs principaux: | , , , , , , , , , , , |
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| Format: | article |
| Langue: | EN |
| Publié: |
Nature Portfolio
2016
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| Sujets: | |
| Accès en ligne: | https://doaj.org/article/f6995303f7fb43f9b1b2cb793eb800e1 |
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