Copper(I)-catalyzed diastereo- and enantio-selective construction of optically pure exocyclic allenes

Substantial efforts have been devoted to the construction of axially chiral allenes, however, the strategies to prepare chiral exocyclic allenes are still rare. This work describes a copper-catalyzed asymmetric synthesis of exocyclic allenes by simultaneous control of axial and central chirality.

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Autores principales: Cheng-Yu He, Yun-Xuan Tan, Xin Wang, Rui Ding, Yi-Fan Wang, Feng Wang, Dingding Gao, Ping Tian, Guo-Qiang Lin
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/f7b8036d46844e46b07e688aa2c62b34
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