Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes

The development of straightforward methods for the synthesis of planar chiral ferrocenes remains highly challenging. Here, the authors report a rhodium(I)/phosphonate-catalyzed thioketone-directed enantioselective C-H bond arylation reaction for the synthesis of chiral planar ferrocenes.

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Autores principales: Zhong-Jian Cai, Chen-Xu Liu, Qiang Wang, Qing Gu, Shu-Li You
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Q
Acceso en línea:https://doaj.org/article/fc4bd478569c4f38963c3027c032091b
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