Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes

The development of straightforward methods for the synthesis of planar chiral ferrocenes remains highly challenging. Here, the authors report a rhodium(I)/phosphonate-catalyzed thioketone-directed enantioselective C-H bond arylation reaction for the synthesis of chiral planar ferrocenes.

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Autores principales:	Zhong-Jian Cai, Chen-Xu Liu, Qiang Wang, Qing Gu, Shu-Li You
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/fc4bd478569c4f38963c3027c032091b
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spelling	oai:doaj.org-article:fc4bd478569c4f38963c3027c032091b2021-12-02T16:58:27ZThioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes10.1038/s41467-019-12181-x2041-1723https://doaj.org/article/fc4bd478569c4f38963c3027c032091b2019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12181-xhttps://doaj.org/toc/2041-1723The development of straightforward methods for the synthesis of planar chiral ferrocenes remains highly challenging. Here, the authors report a rhodium(I)/phosphonate-catalyzed thioketone-directed enantioselective C-H bond arylation reaction for the synthesis of chiral planar ferrocenes.Zhong-Jian CaiChen-Xu LiuQiang WangQing GuShu-Li YouNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Zhong-Jian Cai Chen-Xu Liu Qiang Wang Qing Gu Shu-Li You Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes
description	The development of straightforward methods for the synthesis of planar chiral ferrocenes remains highly challenging. Here, the authors report a rhodium(I)/phosphonate-catalyzed thioketone-directed enantioselective C-H bond arylation reaction for the synthesis of chiral planar ferrocenes.
format	article
author	Zhong-Jian Cai Chen-Xu Liu Qiang Wang Qing Gu Shu-Li You
author_facet	Zhong-Jian Cai Chen-Xu Liu Qiang Wang Qing Gu Shu-Li You
author_sort	Zhong-Jian Cai
title	Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes
title_short	Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes
title_full	Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes
title_fullStr	Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes
title_full_unstemmed	Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes
title_sort	thioketone-directed rhodium(i) catalyzed enantioselective c-h bond arylation of ferrocenes
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/fc4bd478569c4f38963c3027c032091b
work_keys_str_mv	AT zhongjiancai thioketonedirectedrhodiumicatalyzedenantioselectivechbondarylationofferrocenes AT chenxuliu thioketonedirectedrhodiumicatalyzedenantioselectivechbondarylationofferrocenes AT qiangwang thioketonedirectedrhodiumicatalyzedenantioselectivechbondarylationofferrocenes AT qinggu thioketonedirectedrhodiumicatalyzedenantioselectivechbondarylationofferrocenes AT shuliyou thioketonedirectedrhodiumicatalyzedenantioselectivechbondarylationofferrocenes
_version_	1718382306897428480

Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes

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