Chemistry of Spontaneous Alkylation of Methimazole with 1,2-Dichloroethane

Chemistry of Spontaneous Alkylation of Methimazole with 1,2-Dichloroethane

Spontaneous <i>S</i>-alkylation of methimazole (<b>1</b>) with 1,2-dichloroethane (DCE) into 1,2-bis[(1-methyl-1<i>H</i>-imidazole-2-yl)thio]ethane (<b>2</b>), that we have described recently, opened the question about its formation pathway(s). Results...

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Detalles Bibliográficos
Autores principales: Leo Štefan, Ana Čikoš, Robert Vianello, Ivica Đilović, Dubravka Matković-Čalogović, Miljenko Dumić
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
Materias:
1,2-Bis[(1-methyl-1<i>H</i>-imidazole-2-yl)thio]ethane
methimazole
7-methyl-2<i>H</i>,3<i>H</i>,7<i>H</i>-imidazo[2,1-<i>b</i>]thiazol-4-ium salts
thiiranium ion
single-crystal X-ray study
isomerization kinetics
Organic chemistry
QD241-441
Acceso en línea:https://doaj.org/article/fd49ec461dd54c97a020001764d53e54
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https://doaj.org/article/fd49ec461dd54c97a020001764d53e54

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