POLYMERIZATION OF STYRENE BY DIPHENYLZINC-ADDITIVE SYSTEMS. PART X. HOMO- AND COPOLYMERIZATION OF STYRENE USING Ph2Zn - METALLOCENE - MAO SYSTEMS

POLYMERIZATION OF STYRENE BY DIPHENYLZINC-ADDITIVE SYSTEMS. PART X. HOMO- AND COPOLYMERIZATION OF STYRENE USING Ph2Zn - METALLOCENE - MAO SYSTEMS

Combination of diphenylzinc, Ph2Zn, cyclopentadienyl titanium trichloride, CpTiCl3, and methylaluminoxane, MAO, were used to initiate styrene, S, polymerization and its copolymerization with 1-hexadecene, 1-C16H32, and with p-tert-butylstyrene, p-ButS. For homopolymerization an almost pure syndiotat...

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Autores principales: RABAGLIATI,FRANCO M., PÉREZ,MÓNICA. A., CANCINO,RODRIGO A., SOTO,MARCELO A., RODRÍGUEZ,FRANCISCO J., LEÓN,ARTURO G., AYAL,HUGO A., QUIJADA,RAÚL
Lenguaje:English
Publicado: Sociedad Chilena de Química 2000
Materias:
styrene
polymerization
copolymerization
diphenylzinc
metallocenes
catalysts
stereoregularity
tacticity
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442000000200008
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