A THEORETICAL STUDY OF THE STEREOCHEMICAL COURSE OF THE ACID CYCLIZATION OF TWO 5-OXOGERMACREN- 6,12-OLIDES EPIMERIC IN C4

The theoretical study of both the conformational distribution and the acid cyclization of two epimeric 5-oxogermacren-6,12-olides in C4 is described. Our results on the stereochemistry of the cyclization products, 5-hydroxyguaian-6,12-olides, agree with experimental results reported previously. Curt...

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Autores principales: KESTERNICH,VICTOR, CONTRERAS-ORTEGA,CARLOS, MARTINEZ,ROLANDO
Lenguaje:English
Publicado: Sociedad Chilena de Química 2001
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Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442001000300006
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