REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]

REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]

Complex [Mo(NHNPh2)(NNPh2)Br2(acac)], acac=acetylacetonate, reacts in acetonitrile with 1,10-phenanthroline, o-phen, and 2,2’-bipyridine, bpy, to afford complexes [Mo(NNPh2)2Br2(o-phen)], I, and [Mo(NNPh2)2Br2(bpy)], II. These complexes have been characterized by IR, UV-vis and ¹H NMR spectroscopies...

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Auteurs principaux: BUSTOS,CARLOS, MATAMALA,MARCIA, BOYS,DAPHNE, CARRILLO,DAVID
Langue:English
Publié: Sociedad Chilena de Química 2002
Sujets:
hydrazido(1-)
hydrazido(2-)
molybdenum complex
o-phenanthroline
2,2’-bipyridine
X-ray structure
Accès en ligne:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400028
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