REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]

REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]

Complex [Mo(NHNPh2)(NNPh2)Br2(acac)], acac=acetylacetonate, reacts in acetonitrile with 1,10-phenanthroline, o-phen, and 2,2’-bipyridine, bpy, to afford complexes [Mo(NNPh2)2Br2(o-phen)], I, and [Mo(NNPh2)2Br2(bpy)], II. These complexes have been characterized by IR, UV-vis and ¹H NMR spectroscopies...

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Autores principales: BUSTOS,CARLOS, MATAMALA,MARCIA, BOYS,DAPHNE, CARRILLO,DAVID
Lenguaje:English
Publicado: Sociedad Chilena de Química 2002
Materias:
hydrazido(1-)
hydrazido(2-)
molybdenum complex
o-phenanthroline
2,2’-bipyridine
X-ray structure
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400028
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spelling oai:scielo:S0366-164420020004000282009-12-18REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]BUSTOS,CARLOSMATAMALA,MARCIABOYS,DAPHNECARRILLO,DAVID hydrazido(1-) hydrazido(2-) molybdenum complex o-phenanthroline 2,2’-bipyridine X-ray structure Complex [Mo(NHNPh2)(NNPh2)Br2(acac)], acac=acetylacetonate, reacts in acetonitrile with 1,10-phenanthroline, o-phen, and 2,2’-bipyridine, bpy, to afford complexes [Mo(NNPh2)2Br2(o-phen)], I, and [Mo(NNPh2)2Br2(bpy)], II. These complexes have been characterized by IR, UV-vis and ¹H NMR spectroscopies, and elemental analysis. The structure of complex I was solved by single crystal X-ray diffraction. The metal center has a distorted octahedral environment in which the diphenylhydrazido(2-) ligands occupy mutually cis positions but trans to the nitrogen atoms of the o-phen ligand. The bromo ligands occupy mutually trans positions.info:eu-repo/semantics/openAccessSociedad Chilena de QuímicaBoletín de la Sociedad Chilena de Química v.47 n.4 20022002-12-01text/htmlhttp://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400028en10.4067/S0366-16442002000400028
institution Scielo Chile
collection Scielo Chile
language English
topic hydrazido(1-)
hydrazido(2-)
molybdenum complex
o-phenanthroline
2,2’-bipyridine
X-ray structure
spellingShingle hydrazido(1-)
hydrazido(2-)
molybdenum complex
o-phenanthroline
2,2’-bipyridine
X-ray structure
BUSTOS,CARLOS
MATAMALA,MARCIA
BOYS,DAPHNE
CARRILLO,DAVID
REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]
description Complex [Mo(NHNPh2)(NNPh2)Br2(acac)], acac=acetylacetonate, reacts in acetonitrile with 1,10-phenanthroline, o-phen, and 2,2’-bipyridine, bpy, to afford complexes [Mo(NNPh2)2Br2(o-phen)], I, and [Mo(NNPh2)2Br2(bpy)], II. These complexes have been characterized by IR, UV-vis and ¹H NMR spectroscopies, and elemental analysis. The structure of complex I was solved by single crystal X-ray diffraction. The metal center has a distorted octahedral environment in which the diphenylhydrazido(2-) ligands occupy mutually cis positions but trans to the nitrogen atoms of the o-phen ligand. The bromo ligands occupy mutually trans positions.
author BUSTOS,CARLOS
MATAMALA,MARCIA
BOYS,DAPHNE
CARRILLO,DAVID
author_facet BUSTOS,CARLOS
MATAMALA,MARCIA
BOYS,DAPHNE
CARRILLO,DAVID
author_sort BUSTOS,CARLOS
title REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]
title_short REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]
title_full REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]
title_fullStr REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]
title_full_unstemmed REACTIVITY OF[Mo(NHNPh2)(NNPh2)Br2(acac)] TOWARD-DI-IMINES: X-REY CRYSTAL STRUCTURE OF[Mo(NNPh2)2Br2(o-phen)]
title_sort reactivity of[mo(nhnph2)(nnph2)br2(acac)] toward-di-imines: x-rey crystal structure of[mo(nnph2)2br2(o-phen)]
publisher Sociedad Chilena de Química
publishDate 2002
url http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0366-16442002000400028
work_keys_str_mv AT bustoscarlos reactivityofmonhnph2nnph2br2acactowarddiiminesxreycrystalstructureofmonnph22br2ophen
AT matamalamarcia reactivityofmonhnph2nnph2br2acactowarddiiminesxreycrystalstructureofmonnph22br2ophen
AT boysdaphne reactivityofmonhnph2nnph2br2acactowarddiiminesxreycrystalstructureofmonnph22br2ophen
AT carrillodavid reactivityofmonhnph2nnph2br2acactowarddiiminesxreycrystalstructureofmonnph22br2ophen
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