HOMOGENEOUS CATALYSIS OF THE WATER GAS SHIFT REACTION: IR, ¹H- AND 13C-NMR IN SITU STUDIES ON CATALYTIC IRIDIUM SYSTEMS

HOMOGENEOUS CATALYSIS OF THE WATER GAS SHIFT REACTION: IR, ¹H- AND 13C-NMR IN SITU STUDIES ON CATALYTIC IRIDIUM SYSTEMS

Reported here are the in situ FT-IR and 13C-NMR spectroscopic studies of the complex cis-[Ir(CO)2(py)2](PF6 ) (py = pyridine) dissolved in 80% aqueous pyridine used as a precursor in the homogeneous catalysis of the water gas shift reaction (WGSR, CO + H2O Æ CO2 + H2). These spectroscopy studies rev...

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Auteurs principaux: Pardey,A.J., Moreno,M.A., Ortega,M.C., Mendez,B., Rivas,A.B., Moya,S.A., Villagra,D., Lutz,M.
Langue:English
Publié: Sociedad Chilena de Química 2003
Sujets:
Pyridine
WGSR
iridium catalyst
Accès en ligne:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000200003
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http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000200003

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