X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF AN ORGANOMETALLIC HYDRAZONE CONTAINING A ZIGZAG p-CONJUGATED SPACER: [CpFe(h6-C6H5)-N(Me)N=CH-C 6H4-4-NMe2]+ PF6-

X-RAY CRYSTAL AND MOLECULAR STRUCTURE OF AN ORGANOMETALLIC HYDRAZONE CONTAINING A ZIGZAG p-CONJUGATED SPACER: [CpFe(h6-C6H5)-N(Me)N=CH-C 6H4-4-NMe2]+ PF6-

The crystal and molecular structure of the complex [CpFe(h6-C6H5)-N(Me) N=CH-C6H4-4-NMe2]+PF6-, [1]+PF6-, was solved by single crystal X-ray diffraction analysis. One of the most salient features observed in this structure is the depyramidalization of both the benzylic nitrogen and the dimethylamino...

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Autores principales: FIGUEROA,WALTER, FUENTEALBA,MAURICIO, MANZUR,CAROLINA, CARRILLO,DAVID, MATA,JOSE A., HAMON,JEAN-RENÉ
Lenguaje:English
Publicado: Sociedad Chilena de Química 2003
Materias:
hydrazone
iron mixed sandwich
organometallic hydrazone
crystal structure
electronic cooperation
hydrogen bonding
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072003000300015
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