REACTION OF TETRAMENTHYLFULVENE RHENIUM COMPLEXES (η6-C5Me4CH 2)Re(CO)2R (R = I, C6F5) WITH ALKYL PHOSPHINES AND TRIMETHYLPHOSPHITE: X-RAY STRUCTURE OF [(η5-C5Me4CH 2-(PMe3))Re(CO)2(PMe3)]+ I-

REACTION OF TETRAMENTHYLFULVENE RHENIUM COMPLEXES (η6-C5Me4CH 2)Re(CO)2R (R = I, C6F5) WITH ALKYL PHOSPHINES AND TRIMETHYLPHOSPHITE: X-RAY STRUCTURE OF [(η5-C5Me4CH 2-(PMe3))Re(CO)2(PMe3)]+ I-

The fulvene complex (η6-C5Me4CH2 )Re(CO)2(C6F5) 1a reacts with alkyl phosphines to yield the zwitterionic species (η5-C5Me4CH2 PR3)Re(CO)2(C6F 5) 2 (R = Me, Et, iPr). Reaction of the analogous iodo complex (η6-C5Me4CH2 )Re(CO)2I, 1b, with PMe3 and PEt3 affords the cationic...

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Autores principales: GODOY,FERNANDO, KLAHN,HUGO, LAHOZ,FERNANDO, OELCKERS,BEATRIZ, ORO,LUIS A
Lenguaje:English
Publicado: Sociedad Chilena de Química 2004
Materias:
fulvene complexes
functionalized cyclopentadienyl complexes
Acceso en línea:http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072004000300008
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